导师推荐移动版

综合介绍 General Introduction        围绕双位点的构建与调控，通过探索双位点上反应物的吸附和/或中间体的传递行为，在认识和理解先进催化机理的关键科学问题上取得了系列学术成果：揭示了分子在氧化物表面路易斯酸碱双位点上的‘嵌入’式吸附与协同活化机制；发展并完善了氢溢流串联的双位点选择性加氢催化剂的构建方法与作用机理；提出了双位点的空间临近性促进中间体传递过程的学术思想。       以第一和通讯作者在Chem, JACS (2篇), Angew. Chem. Int. Ed. (2篇), Nat. Commun. (3篇)等期刊发表论文40余篇。       主持广东省杰出青年科学基金，入选中国科协“青年人才托举工程”，获得2022年稀土科技技术奖二等奖，陕西省高等学校科技奖一等奖、陕西省优秀博士论文等。 个人相册

教育教学

个人经历 personal experience 工作经历 2020年7月至今，西北工业大学，教授；2017年7月至2020年6月，西安交通大学，讲师。

荣誉获奖

教育教学 Education and teaching 招生信息 化学、化工、应化方面学生，欢迎报考！

科学研究

科学研究 Scientific Research 研究方向：       1. 受阻路易斯酸碱对的构建及应用；       2. 双位点多相催化剂；       3. 绿色催化转化过程。支持项目：6. 深圳市面上项目，主持，在研5. 陕西省重点研发计划一般项目，主持，在研4. 广东省杰出青年基金项目，主持，在研        3. 基于烯烃和CO2合成环状碳酸酯的Au-受阻路易斯酸碱对串联催化的双位点匹配研究，青年基金，主持，在研2. 中国科协青年人才托举工程 配套项目，主持，在研1. 新教师启动经费，主持，在研

学术成果

学术成果 Academic Achievements 2023年                  46. Yong Zou#, Zhaoming Xia#, You Wang, Yuxuan Liu, Sai Zhang* and Yongquan Qu*, Regulation of frustrated Lewis pairs on CeO2 facilitates tandem transformation of styrene and CO2, Chem. Commun. 2023, https://doi.org/10.1039/D3CC03219A.45. Wenbin Li#, Jie Gan#, Yuxuan Liu, Yong Zou, Sai Zhang* and Yongquan Qu*, Platinum and frustrated Lewis pairs on ceria as dual-active sites for efficient reverse water-gas shift reaction at low temperatures, Angew. Chem. Int. Ed. 2023, 62, e202305661.44. Yong Zou, Yuxuan Liu, Sai Zhang* and Yongquan Qu*, Dual active-sites of Co and oxygen vacancies in Co-doped CeO2-catalyzed toluene oxidation for the subsequent Knoevenagel condensation process, Green Chem. 2023, https://doi.org/10.1039/D3GC02466K. 43. Yu Sun, Bing Du, You Wang, Mingkai Zhang and Sai Zhang*, Hydrogen spillover-accelerated selective hydrogenation on WO3 with ppm-Level Pd, ACS Appl. Mater. Interfaces 2023, 15, 20474-20482.42. Ke Xu#, Yu Sun#, You Wang, Bing Du, Xiaolong Li and Sai Zhang*, Electronic property-dependent activity and durability in Pd/C-catalysed hydrogenation of benzoic acid, Chem. Commun. 2023, 59, 5427.41. You Wang#, Bing Liu#, Qing Guo, Yu Sun, Sai Zhang* and Yongquan Qu*, Stabilized *OH species by K+-doped Pt for H2 generation with ultra-low levels of CO through aqueous-phase reforming of methanol at low temperature, Appl. Catal. B-Environ. 2023, 338, 123011.40. Sai Zhang, Zhimin Tian, Yuanyuan Ma and Yongquan Qu*, Adsorption of Molecules on Defective CeO2 for Advanced Catalysis, ACS Catal. 2023, 13, 4629-4645.39. Mingkai Zhang, Sai Zhang* and Yuanyuan Ma*, In-situ reconstruction of CoBOx enables formation of Co for synthesis of benzylamine through reductive amination, Front. Chem. 2023, 10, 1104844. 38. Sai Zhang*, Zhaoming Xia*, Wenbin Li, You Wang, Mingkai Zhang, Zhongmiao Gong, Yi Cui and Yongquan Qu*, In-situ reconstruction of single-atom Pt on Co3O4 for hydrogenation, Nano Res. 2023, 16, 6507-6511.2022年                  37. Sai Zhang, Yuxuan Liu, Mingkai Zhang, Yuanyuan Ma, Jun Hu* and Yongquan Qu*, Sustainable production ofhydrogen with high purity from methanol and water at low temperatures, Nat. Commun. 2022, 13, 5527.36. Mingkai Zhang*, Yu Sun*, Xuemei Han, Wangxing Guo, Ziheng Cheng, Yong Zou and Sai Zhang*, Modifying Interface of Carbon Support-Stimulated Hydrogen Spillover for Selective Hydrogenation, J. Phys. Chem. C 2022, 126, 16682-16689.  35. Yong Zou, Mingkai Zhang, Yuxuan Liu, Yuanyuan Ma, Sai Zhang* and Yongquan Qu*, Highly selective transfer hydrogenation of furfural into furfuryl alcohol by interfacial frustrated Lewis pairs on CeO2, J. Catal. 2022, 410, 54-62. 34. Mingkai Zhang, Yong Zou, Sai Zhang* and Yongquan Qu*, Modulated electronic structure of Pd nanoparticles on Mg(OH)2 for selective benzonitrile hydrogenation into benzylamine at a low temperature, Inorg. Chem. Frount. 2022, 9, 4899-4906.33. Mingkai Zhang, Yong Zou, Sai Zhang* and Yongquan Qu*, In situ Re-construction of Pt Nanoparticles Interface for Highly Selective Synthesis of Primary Amines, ChemCatChem 2022, e202200176.32. Yu Sun, Mingkai Zhang, Yong Zou, Hepeng Zhang* and Sai Zhang*, Size-Dependent Pt Nanoparticle/Carbon-Catalyzed Hydrogenation of 6-Chloroquinoline, ACS Appl. Nano Mater. 2022, 5, 4252-4259.31. Xiao Chen#, Yong Zou#, Mingkai Zhang, Wangyan Gou, Sai Zhang* and Yongquan Qu*, Multiscale porous single-atom Co catalysts for epoxidation with O2, J. Mater. Chem. A 2021, 10, 6016-6022.2021年                                     30. Yong Zou, Mingkai Zhang, Fangxian Cao, Jiayuan Li, Sai Zhang* and Yongquan Qu*, Single crystal MnOOH nanotubes for selective oxidative coupling of anilines to aromatic zao compounds, J. Mater. Chem. A 2021, 9, 19692-19697.29. Sai Zhang#, Zhaoming Xia#, Yong Zou, Mingkai Zhang and Yongquan Qu*, Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines, Nat. Commun. 2021, 12, 3382.28. Sai Zhang*, Zhaoming Xia, Mingkai Zhang, Yong Zou, Haidong Shen, Jiayuan Li, Xiao Chen and Yongquan Qu*, Boosting selective hydrogenation through hydrogen spillover on supported-metal catalysts at room temperature, Appl. Catal. B-Environ. 2021, 297, 120418.27. Zechen Liang, Mingkai Zhang, Sai Zhang* and Yongquan Qu*, Electron-Enriched Pd Nanoparticles for Selective Hydrogenation of Halonitrobenzenes to Haloanilines, Catalysts 2021, 11, 543. Invited paper.2020年                                   26. Sai Zhang#, Jie Gan#, Zhaoming Xia, Xiao Chen, Yong Zou, Xuezhi Duan and Yongquan Qu*, Dual-active-sites design of Co@C catalysts for ultrahigh selective hydrogenatoin of N-heteroarenes, Chem 2020, 6, 2994-3006. 25. S. Zhang#, Z. M. Xia#, Y. Zou, F. X. Cao, Y. X. Liu, Y. Y. Ma, Y. Q. Qu*. Interfacial frustrated Lewis pairs of CeO2 activate CO2 for selective tandem transformation of olefins and CO2 into cyclic carbonates, J. Am. Chem. Soc. 2019, 141, 11353-11357.24. S. Zhang, C. R. Chang, Z. Q. Huang, J. Li, Z. M. Wu, Y. Y. Ma, Z. Y. Zhang, Y. Wang and Y. Qu*, High catalytic activity and chemoselectivity of sub-nanometric Pd clusters on porous nanorods of CeO2 for hydrogenation of nitroarenes. J. Am. Chem. Soc., 2016, 138, 2629-2638.（ESI高被引论文）23. S. Zhang#, Z. Q. Huang#, Y. Y. Ma, W. Gao, J. Li, F. X. Cao, L. Li, C. R. Chang*, Y. Qu*. Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2, Nat. Commun., 2017, 8, 15266. 22. S. Zhang, Y. Ma, H. Zhang, X. Zhou, X. Chen and Y. Qu*, Additive-free, robust and high value-added H2 production from H2O and DMF by dehydrogenation catalyzed by Cu/Cu2O formed in situ. Angew. Chem. Int. Ed. 2017, 56, 8245-8249. 21. S. Zhang, C. R. Chang, Z. Q. Huang, Y. Y. Ma, W. Gao, J. Li and Y. Qu*, Visible-light-activated Suzuki-Miyaura coupling reactions of aryl chlorides over the multifunctional Pd/Au/porous nanorods of CeO2 catalysts. ACS Catal. 2015, 5, 6481-6488.20. S. Zhang, Z. M. Xia, Y. Y. Ma, J. Li, Y. Q. Qu*. Competitive adsorption on PtCo/CoBOx catalysts enables the selective hydrogen-reductive-imination of nitroarenes with aldehydes into imines. J. Catal. 2019, 374, 72-81.19. S. Zhang#, Z. Q. Huang#, X. Chen, J. Gan, X. Z. Duan, C. R. Chang*, Y. Q. Qu*. Hydrogen activation enabled by the interfacial frustrated Lewis pairs on cobalt borate nanosheets, J. Catal., 2019, 372,142-150.18. S. Zhang, Z. M. Xia, T. Ni, Z. Y. Zhang, Y. Y. Ma and Y. Q. Qu*, Strong electronic metal-support interaction of Pt/CeO2 enables efficient and selective hydrogenation of quinolines at room temperature. J. Catal. 2018, 359, 101-111.17. X. M. Han, X. Chen, Y. Zou, S. Zhang*, Electronic state regulation of supported Pt catalysts dictates selectivity of imines/secondary amines from the cascade transformation of nitroarenes and aldehydes. Appl. Catal. B-Environ. 2019, 118451.16. X. Chen, H. Zhang, M. K. Zhang, Y. Zou, S. Zhang* and Y. Q. Qu*, Temperature-responsive dissolution/recrystallization of Zn MOF enables the maximum efficiency and recyclability of catalysts, Chem. Common. 2020, 56, 1960-1963.15. Sai Zhang, Mingkai Zhang and Yongquan Qu*, Solid frustrated Lewis pairs construcuted on CeO2 for small-molecule activation, Acta Phys.-Chim. Sin., 2020, 36, 1911050. 14. S. Zhang, Z. M. Xia, T. Ni, H. Zhang, C. Wu, Y. Qu*. Tuning chemical compositions of bimetallic AuPd catalysts for selective catalytic hydrogenation of halogenated quinolines. J. Mater. Chem. A, 2017, 5, 3260-3266.（hot paper）13.   S. Zhang, X. T. Shen, Z. P. Zheng, Y. Ma and Y. Qu*, 3D graphene/nylon rope as a skeleton for noble metal nanocatalysts for highly efficient heterogeneous continuous-flow reactions. J. Mater. Chem. A, 2015, 3, 1050-10511.12. S. Zhang, H. Zhang, F. X. Cao, Y. Y. Ma, Y. Q. Qu*. Catalytic behavior of graphene oxides for converting CO2 into cyclic carbonates at one atmospheric pressure, ACS Sustainable Chem. Eng., 2018, 6, 4204-421111. X. Chen, H. Zhang, Z. M. Xia, S. Zhang*, and Y. Y. Ma*. Base-free hydrogen generation from formaldehyde and water catalyzed by copper nanoparticles embedded on carbon sheets. Catal. Sci. Technol. 2019, 9, 783-788.10. T. Ni, H. Zhang, S. Zhang*, Room-temperature hydrogen generation from water and nanoscale Fe catalyzed by Pd. Inorg. Chem. Front., 2019, 6, 257-262. 9. S. Zhang#, Z. M. Xia#, X. Chen, W. Gao, Y. Q. Qu*. Selective semi-hydrogenation of phenylacetylene into styrene catalyzed by alloyed PdAu catalysts anchored on CeO2, ChemNanoMat, 2018, 4, 427-476.8. S. Zhang#, J. Li#, Z. M. Xia#, C. Wu, Z. Y. Zhang, Y. Ma, Y. Qu*. Towards highly active Pd/CeO2 for alkene hydrogenation by tuning Pd dispersion and surface properties of catalysts. Nanoscale, 2017, 9, 3140-3149.7. S. Zhang*, H. Zhang, T. Ni, X. T. Shen, Highly efficient Au nanocatalysts for heterogeneous continuous-flow reactions using hollow CeO2 microspheres as a functional skeleton. Ind. Eng. Chem. Res., 2018, 57, 3575-3582.6. T. Ni, S. Zhang*, F. X. Cao and Y. Y. Ma*, NiCo bimetallic nanoparticles encapsulated in graphite-like carbon layers as efficient and robust hydrogenation catalysts. Inorg. Chem. Front., 2017, 4, 2005-2011.5. S. Zhang, J. Li, W. Gao, and Y. Qu*, Insights into the effects of surface properties of oxides on the catalytic activity of Pd for C-C coupling reactions. Nanoscale, 2015, 7, 3016–8022.4. S. Zhang, W. Gao, J. Li, X. M. Zhou and Y. Qu*, Interfacial effects of the CuO/GO composite to mediate the side reactions of N,N-Dimethylformamide fragments. ACS Appl. Mater. Interfaces, 2014, 6, 22174-22182. 3. S. Zhang, Y. Zhou*, W. Nie, L. Song, J. Li and B. Yang, Fabrication of uniform “smart” magnetic microcapsules and their controlled release of sodium salicylate. J. Mater. Chem. B, 2013, 1, 4331-4337.2. S. Zhang, Y. Zhou*, W. Nie, L. Song and T. Zhang, Preparation of uniform magnetic chitosan microcapsules and their application in adsorbing copper ion(II) and chromium ion(III). Ind. Eng. Chem. Res. 2012, 51, 14099-14106.1. S. Zhang, Y. Zhou*, W. Nie, L. Song, Preparation of Fe3O4/chitosan/poly(acrylic acid) composite particles and its application in adsorbing copper ion (II). Cellulose, 2012, 19, 2081-2091.

综合介绍